Madison Township - northwest, across the Great Miami River.Deerfield Township, Warren County - southeast.Turtlecreek Township, Warren County - northeast.Today, the township is located in the eastern part of the county and borders the following townships: The original boundaries included what is now West Chester Township, which was separated from Liberty Township by the Butler County Commissioners on June 2, 1823. Unincorporated places are Bethany, Four Bridges, Hughes Station, Kyles Station, Jericho, and Princeton. The northeast corner of the township is part of the city of Monroe, the sole municipality in Liberty Township. It is one of 25 Liberty Townships statewide. The first settler was John Nelson, who arrived in 1796, seven years before Ohio became a state. It was named for Liberty, Pennsylvania, at the suggestion of John Morrow, a resident in the township at the time of its formation in 1803 who was the brother of Ohio Governor Jeremiah Morrow, after his hometown.

It is located on the east-central part of the county, just south of the city of Monroe. The population was 43,999 at the 2020 census. It is one of thirteen townships in Butler County, Ohio, United States.

Liberty Township is an affluent suburb of Cincinnati located in Butler County, Ohio.

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